PPKTP Crystals

Features:

  • Periodically poled potassium titanyl phosphate (PPKTP) is a high-performance nonlinear crystal.
  • Unique structure for efficient quasi-phase matching (QPM).
  • High conversion efficiency across a broad range of nonlinear optical processes (350–4000 nm).
PPKTP Crystal

Applications:

  • SPDC: Spontaneous parametric down-conversion, used in quantum optics for creating entangled photon pairs and other quantum processes.
  • SHG: Second harmonic generation, typically used to produce green light from 1 µm lasers.
  • SFG: Sum frequency generation, applied in up-conversion detection, spectroscopy, and biomedicine.
  • DFG: Difference frequency generation, used in creating mid-infrared laser sources for spectroscopy, sensing, and communication.
  • BW-OPO: Backward wave optical parametric oscillator, which enhances conversion efficiency and stability by splitting the pump beam into forward and backward propagating waves.

Customization Information:

  • Provide pump wavelength, signal wavelength, or idle wavelength.
  • Periodicity requirement (if applicable).
  • Crystal dimensions (minimum X: 30mm).
  • Aperture size (W x Z: up to 4 x 4 mm²).
  • Coating requirements.
PPKTP Crystal 2

Specifications:

PropertyValue
Flatnessλ/8 at 633 nm
Parallelism< 20 arcsec
Surface Quality10 – 5 scratch & dig (MIL-PRF-13830B)
Perpendicularity< 5 arcmin
Angle Tolerance< 30 arcmin
Aperture Tolerance± 0.1 mm
Clear Aperture90% of full aperture

Physical Properties:

PropertyValue
Crystal StructureOrthorhombic
Point Groupmm2
Space GroupPna2₁
Lattice Constants (Å)a = 6.404, b = 10.616, c = 12.814, z = 8
Density (g/cm³)3.01
Melting Point (°C)1172
Transition Temperature (°C)936
Mohs Hardness5
Thermal Expansion Coefficients (°C⁻¹)αₓ = 11×10⁻⁶, αᵧ = 9×10⁻⁶, α_z = 0.6×10⁻⁶
Thermal Conductivity (W/cm°C)13
Not HygroscopicYes

Optical Properties:

PropertyValue
Transparency Range (nm)350–4400
Refractive Indices@1064 nm: nₓ = 1.7404, nᵧ = 1.7497, n_z = 1.8296<br>@532 nm: nₓ = 1.7797, nᵧ = 1.7897, n_z = 1.8877
Thermooptic Coefficients (0.4–1.0 µm range)dnₓ/dT = 1.1×10⁻⁵ (K⁻¹), dnᵧ/dT = 1.3×10⁻⁵ (K⁻¹), dn_z/dT = 1.6×10⁻⁵ (K⁻¹)
Wavelength Dispersion of Refractive Indicesnₓ² = 3.0067 + 0.0395/(λ² – 0.04251) – 0.01247λ²<br>nᵧ² = 3.0319 + 0.04152/(λ² – 0.04586) – 0.01337λ²<br>n_z² = 3.3134 + 0.05694/(λ² – 0.05941) – 0.01671λ²

Nonlinear Properties:

PropertyValue
Phase Matching Range for Type 2 SHGx-y plane: 0.99–1.08 µm<br>x-z plane: 1.1–3.4 µm
Walk-off4 mrad
Angular AcceptancesΔθ = 55 mrad × cm
Spectral AcceptancesΔν = 0.56 nm × cm
Thermal AcceptanceΔT = 22 K × cm
Effective Nonlinearityx-y plane: dₑₒₑ = d₁₅sin²ϕ + d₂₄cos²ϕ<br>x-z plane: d₁₅sinθ, d₁₅ = 1.95 pm/V, d₃₂ = 3.9 pm/V, d₃₃ = 15.3 pm/V, d₂₄ = 1.95 pm/V
Damage Threshold> 500 MW/cm² for pulses λ = 1064 nm, τ = 10 ns, 10 Hz, TEM₀₀

PPKTP crystals from Shape Optics provide high performance and efficiency for a wide range of nonlinear optical applications. With our high-quality manufacturing process, you can be assured of the best conversion efficiencies and broad transparency range for your specific needs. Contact us today to learn how PPKTP crystals can enhance your optical systems.