Chromium Doped Yttrium Aluminum Garnet (Cr4+) Crystal Properties – Shape Optics

Key Features:

  • Wide absorption band (0.8 to 1.2 µm)
  • High damage threshold (>500 MW/cm²)
  • High extinction ratio
  • Temperature stability
  • Long operational lifespan

Cr4+:YAG Crystal

Description:

Cr4+(Chromium Doped Yttrium Aluminum Garnet) is an excellent passive Q-switch material for Nd, Nd, Nd₄, and other lasers operating in the 0.8 to 1.2 µm wavelength range. Cr4+crystals enable efficient passive Q-switching, which allows for the generation of short, high-intensity laser pulses without the need for an external electrical signal. This property eliminates the need for high-voltage power supplies, making Cr4+crystals an ideal choice for compact and reliable Q-switch applications.

The broad absorption band of Cr4+makes it versatile for various laser types, providing consistent performance and stability. Cr4+is widely recognized for its high damage threshold, ensuring durability and long-term reliability in high-power laser systems. It is one of the most commonly used passive Q-switch materials in the industry.


Physical Properties:

  • Chemical Formula: Cr4+₃Al₅O₁₂
  • Crystal Structure: Cubic
  • Density: 4.56 g/cm³
  • Hardness: Mohs 8.5
  • Melting Point: 1970°C

Optical Properties:

  • Absorption Wavelength Range: 0.8 to 1.2 µm
  • Emission Wavelength: 950-1100 nm
  • Refractive Index: 1.82 at 1064 nm
  • Birefringence: None (isotropic)

Standard Specifications:

  • Available Sizes: 3×3×20 mm² to 20×20×20 mm²
  • Aperture: Customizable
  • Surface Quality: 10-5 scratch-dig
  • Flatness: <λ/10 @ 632 nm
  • Parallelism: ≤ 20 arc seconds
  • Perpendicularity: ≤ 15 arc minutes
  • Chamfer: <0.25 mm @ 45°
  • Coating: AR/AR @ 1064 nm (R < 0.2%)

Other Properties:

  • High damage threshold: >500 MW/cm² (10 ns pulse width at 1064 nm)
  • High extinction ratio: Ensures efficient Q-switching and pulse generation

Applications:

  • Passive Q-switch for Nd, Nd, Nd₄, and other lasers
  • High-power laser systems
  • Medical lasers
  • Industrial lasers
  • Military and aerospace laser applications

Processing and Handling:

  • Cr4+crystals should be handled with care to avoid contamination and surface damage.
  • Store crystals in a clean, dry environment to maintain optimal performance.
  • Use appropriate mounting techniques to ensure stable and reliable operation.

Why Choose Shape Optics:

  • Precision crystal growth and fabrication
  • Advanced coating capabilities
  • Customizable sizes and specifications to meet diverse application needs
  • Rigorous quality control ensuring high performance and reliability

Shape Optics Strength and Capabilities:

Shape Optics is dedicated to providing high-quality optical components tailored to the specific needs of our customers. Our expertise in crystal growth, coating technologies, and rigorous quality control processes ensure that our Cr4+crystals deliver exceptional performance and reliability. Partner with Shape Optics for innovative solutions and unparalleled support in your optical applications.